The exactly Explanation of negative Ions

The correct explanation of an adverse ions is entirely different from the matter of completing a shell of eight. Very first it is crucial to consider some aspects of electrostatic charge.When a fee is dispersed uniformaly on a spherical covering it has the impact on another charge external of the round equal come what that same charge would have concentrated at the center of the sphere. ~ above the various other hand, the result on a charge within the ball is zero. What is left the end is the result of a charge spread on a spherical covering on a charge situated on particles located at the middle of that dispersed charge. That impact is equal to what half the fee would have actually located in ~ the facility of the sphere. Thus if the number of electrons in a covering is denoted as ε1and there room ε0 electrons located internal to the shell then the reliable charge Z exhilaration on one electron in the shell is Z = ns − ε0 − ½(ε1-1) whereby p is the number of protons in the nucleus.Thus the energy required to eliminate an electron native a shell have to decrease with the variety of electrons in the shell. This is as result of the shielding of several of the hopeful charge that the cell nucleus by electrons in the same-shell. Negative charged ion are developed when an atom acquires enough electrons to finish a shell. For example, the fluorine atom has actually nine protons and nine electrons. There space two electrons in the first shell and also seven in the second shell. The volume of the 2nd shell is eight. The fluorine ion F- has a net an adverse charge yet the electrons space some just how clinging come it. The concept of shielding of electron in the same-shell provides a different sort that justification because that the F-. The 2 electrons in the within shell totally shield two protons. For any type of electron in the 2nd shell there are seven other electrons in the very same shell, every shielding a fifty percent unit of hopeful charge each. The make the charge competent by the eighth electron in the second shell equal to (9-2-½(7))=3.5 optimistic charges. The is enough to organize that eighth electron in the second shell.An oxygen nucleus has actually 8 protons and 8 neutrons. There are two electron in the very first shell. In the oxygen atom thereare six electrons in the second shell. The net hopeful charge competent by a saturday electron in the second shell is(8−2−½6)=3. Hence it would certainly be hosted as tightly as the third electron in a lithium atom; i.e., no stronglybut definitely held. The eighth electron in the 2nd shell that oxygen would endure a net confident charge of (8−2−½7)=2.5. Again absolutely there is a hopeful attraction stop the eighth electron in the O2- ion.The truth is more facility but this computation describes how the extra electron in negatively charged ion could be clinging to a device with no net hopeful charge. Exterior of the last shell the ion has a net an adverse charge but withinthe last shell there is a net optimistic charge due to the fact that of the fractional same-shell shielding.The higher chemical task of fluorine contrasted to oxygen is at some time thought to be because fluorine is just oneshort of completing a covering of eight when oxygen is 2 short. That is no the case. Fluorine has actually a more powerfulattraction because that an eighth electron in the second shell than does oxygen due to the fact that fluorine has actually nine protons in the nucleusand oxygen has only eight. Thus the net confident charge experienced by the eighth electron because that fluorine is 3.5 whereasfor oxygen the is only 2.5. For this reason fluorine more readily creates ions 보다 oxygen and fluorine is an ext active chemicallythan oxygen.For salt the next electron is in the third shell. Every one of the electron in the second shell then complete shield eightunits of charge in the nucleus. Therefore the net optimistic charge skilled by the first electron in the 3rd shellis (11−2−8)=1. A sodium atom thus an extremely easily relinquishes that electron in the third shell. The network chargeexperienced by the second electron in the 3rd shell because that a magnesium atom is (12−2−8−½1)=1.5.


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Therefore that last electron is an ext tightly held by a magnesium atom and also positivemagnesium ion are much less readily created than sodium ions. Hencemagnesium is much less chemically energetic than sodium.HOME page OF applet-magicHOME page OF Thayer Watkins
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